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lithium tetrafluoroborate : ウィキペディア英語版
lithium tetrafluoroborate

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Lithium tetrafluoroborate is an inorganic compound with the formula LiBF4. It is a white crystalline powder. It has been extensively tested for use in commercial secondary batteries, an application that exploits its high solubility in nonpolar solvents.〔Xu, Kang. "Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries."Chemical Reviews 2004, volume 104, pp. 4303-418. 〕
==Applications==
Although BF4 has high ionic mobility, solutions of its Li+ salt are less conductive than other less associated salts.〔 As an electrolyte in Lithium-ion batteries, LiBF4 offers some advantages relative to the more common LiPF6. It exhibits greater thermal stability and moisture tolerance. For example LiBF4 can tolerate a moisture content up to 620 ppm at room temperature whereas LiPF6 readily hydrolyzes into toxic POF3 and HF gases, often destroying the battery's electrode materials. Disadvantages of the electrolyte include a relatively low conductivity and difficulties forming a stable solid electrolyte interface with graphite electrodes.

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